In CBSE Class 10 Science board examinations, practical-based questions (PBQs) carry marks across Section B and Section C. Unlike theoretical questions that ask for textbook definitions, practical questions present laboratory observations: "A student heats a green crystalline powder in a dry test tube... A gas with the smell of burning sulfur is evolved... A white precipitate turns milky..."
To secure full marks on observational chemistry questions, students must memorize the diagnostic confirmatory tests for evolved gases, characteristic flame colors, and color changes of common inorganic salts.
In this master guide, we compile the definitive Qualitative Chemistry Diagnostic Guide for Class 10 Science.
What You Will Learn
- Confirmatory identification tests for all major laboratory gases: and
- The Lime Water Test for Carbon Dioxide: Why excess causes milkiness to disappear
- Color transformations of common salts upon heating (Thermal Decomposition Diagnostics)
- The action of acids on metals, metal carbonates, and metal oxides
- High-yield observational question templates and common exam pitfalls
1. Confirmatory Tests for Common Laboratory Gases
Evolved Gas Sensory Clue Confirmatory Laboratory Test
----------------------------------------------------------------------------------------------------------
Hydrogen (H₂) Colourless, odourless Burns with a characteristic 'POP' SOUND
when a burning wooden splinter is brought near!
Carbon Dioxide (CO₂) Colourless, brisk effervescence Turns clear LIME WATER MILKY!
(Milkiness disappears on passing EXCESS CO₂).
Oxygen (O₂) Colourless, odourless REKINDLES a glowing wooden splint.
Sulphur Dioxide (SO₂) Suffocating, CHOKING smell Turns acidified potassium dichromate (K₂Cr₂O₇)
of burning sulfur solution from ORANGE to GREEN!
Chlorine (Cl₂) Greenish-yellow gas, pungent BLEACHES moist litmus paper (acts as bleach).
----------------------------------------------------------------------------------------------------------
2. The Complete Chemistry of the Lime Water Test ()
The reaction of carbon dioxide with lime water is the most frequently tested experimental question in CBSE Chemistry:
Step 1: Passing Limited CO₂ (MILKINESS APPEARS!)
Ca(OH)₂ (aq) [Clear Lime Water] + CO₂ (g) ───> CaCO₃ (s) ↓ [WHITE PRECIPITATE] + H₂O (l)
(Causes the cloudy milkiness!)
Step 2: Passing Excess CO₂ (MILKINESS DISAPPEARS!)
CaCO₃ (s) + H₂O (l) + CO₂ (g) [Excess] ───> Ca(HCO₃)₂ (aq) [SOLUBLE Calcium Bicarbonate]
(Completely dissolves, turning solution CLEAR again!)
Important: <u>Why does the milkiness disappear when excess carbon dioxide is passed through lime water? Because insoluble white calcium carbonate () reacts with excess and water to form calcium hydrogen carbonate , which is completely SOLUBLE in water!</u>
3. Salt Transformations upon Heating (Thermal Decomposition)
When white or colored powders are heated in a dry boiling tube:
| Starting Compound | Initial Appearance | Observation on Heating | Residue Left Behind |
|---|---|---|---|
| Ferrous Sulphate () | Pale green crystals | Turns white, then evolves choking gases | Reddish-brown solid () |
| Lead Nitrate [] | White powder | Crackling sound, evolves dense brown fumes () | Yellow solid () |
| Copper Carbonate () | Green powder | Evolves gas with brisk effervescence | Black solid () |
| Zinc Oxide () | White powder | Turns YELLOW when hot, turns WHITE when cold | Reversible physical change |
| Hydrated Copper Sulphate () | Deep blue crystals | Loses water of crystallization, turns white | Turns blue again when water is added! |
4. Reactions of Acids with Metals and Carbonates
1. Metal + Acid Salt + Hydrogen Gas ()
- Zinc granules react with dilute sulphuric acid; bubbles of hydrogen gas emerge, which burn with a pop sound when tested with a candle.
2. Metal Carbonate + Acid Salt + Water + Carbon Dioxide ()
- Produces brisk effervescence; passing the gas into lime water turns it milky.
5. Summary and Examination Tips
| Experimental Observation | Inferred Compound / Gas | Confirmatory Reaction |
|---|---|---|
| Pop sound with burning flame | Hydrogen Gas () | |
| Lime water turns milky | Carbon Dioxide () | Forms precipitate |
| Choking sulfur smell | Sulphur Dioxide () | Turns orange dichromate to green |
| Brown fumes from white powder | Lead Nitrate / gas |
Exam Tip: In questions where an unknown metal reacts with dilute acid to evolve a gas: if the gas burns with a pop sound, it is Hydrogen ()! If it turns lime water milky, the starting substance was a Carbonate or Bicarbonate () evolving Carbon Dioxide ()!
Common Mistake: Confusing the gas that turns lime water milky () with the gas that turns acidified potassium dichromate green (). Both are non-metal oxides, but has a strong choking smell, whereas is odorless!